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Sku 44-0167-50MG
STREM
Technical Notes: 1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2) 2.The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen. References: 1. J. Org. Chem., 1996, 61, 5510. 2. Topics Organometal. Chem. 2004, 6, 63 (review). |