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Sku 44-0094-50MG
STREM
Technical Notes: 1.. Biary bisphosphine ligand. The Hg-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2) 2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen. References: 1. J. Org. Chem., 1996, 61, 5510. 2.Topics Organometal. Chem. 2004, 6, 63 (review). |