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(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
$396.00
Technical Notes:1. Efficient catalyst for the e nantioselective hydrosilyation of 1 -alkenes to optically active 2-alcohols.2.Ligand for palladium-catalyzed asymmetric reduction of allylic esters ,3: L igand for the rhodium catalyzed...
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Sku: 15-1775-500MG
STREM
| Technical Notes: 1. Efficient catalyst for the e nantioselective hydrosilyation of 1 -alkenes to optically active 2-alcohols. 2.Ligand for palladium-catalyzed asymmetric reduction of allylic esters , 3: L igand for the rhodium catalyzed asymmetric arylation of imines with organostannanes . 4. L igand for the rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to Isatins. 5. Ligand for desymmetrization of malonamides via an enantioselective intramolecular Buchwald-Hartwig reaction. References: 1. J. Am. Chem. Soc.. 1991, 1 13, 9887. 2.Acc. Chem. Res., 2000, 33, 354. (review) . 3.J. Am. Chem. Soc., 1994, 116, 775. 4. J. Am. Chem. Soc., 2000, 122, 976. 5.Angew. Chem. Int. Ed.. 2006, 45, 3353. 6. Tetrahedron L ett., 2009, 50, 41 70 |
