N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-[(11bR)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]thiourea, 98%, (99% ee)

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Sku 07-6335-50MG
STREM
Technical Notes:
1.Michael Addition to promote enantioselective Michael re action between 1 ,3-dicarbonyl compounds and nitroolefins.
2.Spirocyclopentaneoxindoles with four contiguous stereocenters including one spiroquaternary stereocenter are synthesized by a combined Ru-catalyzed cross-metathesis/organocatalyzed asymmetric double-Michaeladdition.
3.Catalytic enantioselective conjugate addition reaction of a-fluoro-ß-ketoesters to nitroalkenes .
4.Catalytic enantiosele ctive electrophilic a-hydrazination promoted by chiral bifunctional organocatalysts .
5.Catalytic enantioselective Mannich reaction promoted by chiral bifunctional organocatalysts.