{"product_id":"q8826-1175","title":"(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97% | 851308-40-2","description":"\u003cstyle\u003e\n  \/* isQuote *\/\n  div.swatch.clearfix {\n    display:  unset ;\n  }\n\n  \/* Hide sku *\/\n  .product-sku, \n  #leadtimetext {\n    display: none !important;\n  }\n\n  \/* Square brackets *\/\n  span.l_bracket:before {\n    content: \"[\";\n  }\n  span.r_bracket:after {\n    content: \"]\";\n  }\n\n  \/* Hazard Symbols *\/\n  .ghs-symbols-row {\n    display: flex;\n    flex-wrap: wrap;\n    gap: 10px;\n  }\n\n  .hazard-symbol-container {\n    width: 50px;\n  }\n\n  .hazard-symbol {\n    object-fit: contain;\n    aspect-ratio: 1 \/ 1;\n    width: 100%;\n  }\n\n  \/* Section *\/\n  .section-header {\n    font-size: 1.5rem;\n    font-weight: bold;\n    color: #239ab7;\n    background-color: #f2f2f2;\n    padding: 10px;\n    border-radius: 4px;\n  }\n\n  .section-row {\n    display: grid;\n    grid-template-columns: repeat(8, 1fr);\n    padding: 6px 10px;\n    border-bottom: 1px solid #e0e0e0;\n  }\n\n  .section-content {\n    padding-bottom: 6px;\n  }\n\n  .section-content .section-row:last-child {\n    border-bottom: none;\n  }\n\n  .section-row .row-key {\n    grid-column: 1 \/ 3;\n    font-weight: bold;\n    align-self: center;\n  }\n\n  .section-row .row-value {\n    grid-column: 3 \/ 9;\n  }\n\n  .section-row ul li {\n    line-height: 2rem !important;\n    font-size: 1.3rem;\n  }\n\n  .html-area {\n    padding: 10px;\n  }\n\n  .html-area {\n    padding: 10px;\n  }\n\n  .html-area p {\n    margin: 0 !important;\n  }\n\n  .hazard-grid {\n    display: grid;\n    grid-template-columns: repeat(6, 1fr);\n    gap: 0 10px;\n    font-size: 1.3rem;\n  }\n\n  .reference-item {\n    padding: 10px 10px;\n    border-bottom: 1px solid #e0e0e0;\n  }\n\n  .section-content .reference-item:last-child {\n    border-bottom: none;\n  }\n\n  .reference-item h3 {\n    font-size: 1.5rem !important;\n  }\n\n  .reference-item .publication-item {\n    font-size: 1.3rem !important;\n    line-height: 1.5rem !important;\n  }\n\n  \/* SDS Search *\/\n  .section-row .coa-search-container {\n    display: flex;\n    align-items: center;\n    margin-top: 6px;\n  }\n\n  .section-row .coa-search-container input {\n    border: 1px solid #e0e0e0;\n    height: 2.5rem;\n    border-top-left-radius: 0.5rem !important;\n    border-bottom-left-radius: 0.5rem !important;\n    padding: 3px 5px;\n  }\n\n  .section-row .coa-search-container button {\n    height: 2.5rem;\n    line-height: 2.5rem;\n    border-radius: 0 0.5rem 0.5rem 0;\n  }\n\n  .section-row .coa-search-container button .coa-search-button-content {\n    display: flex;\n    align-items: center;\n    justify-content: center;\n    gap: 3px;\n  }\n\n  .section-row .coa-search-container button .coa-search-button-content .search-spin {\n    display: none;\n    width: 2rem;\n  }\n\n  .section-row .coa-search-container .coa-not-found {\n    display: none;\n 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Name\u003c\/div\u003e\n            \u003cdiv class=\"row-value\"\u003e(R)-(-)-1-\u003cspan class=\"l_bracket\"\u003e\u003c\/span\u003e(S)-2-(Di-1-naphthylphosphino)ferrocenyl\u003cspan class=\"r_bracket\"\u003e\u003c\/span\u003eethyldi-3,5-xylylphosphine, min. 97%\u003c\/div\u003e\n        \u003c\/div\u003e\n        \n        \n        \n        \u003cdiv class=\"section-row\"\u003e\n            \u003cdiv class=\"row-key\"\u003eBrand Name\u003c\/div\u003e\n            \u003cdiv class=\"row-value\"\u003eUS-Strem\u003c\/div\u003e\n        \u003c\/div\u003e\n        \n\n        \n        \u003cdiv class=\"section-row\"\u003e\n            \u003cdiv class=\"row-key\"\u003eProduct Number\u003c\/div\u003e\n            \u003cdiv class=\"row-value\"\u003e26-1175\u003c\/div\u003e\n        \u003c\/div\u003e\n        \n\n        \n        \u003cdiv class=\"section-row\"\u003e\n            \u003cdiv class=\"row-key\"\u003eCAS\u003c\/div\u003e\n            \u003cdiv class=\"row-value\"\u003e851308-40-2\u003c\/div\u003e\n        \u003c\/div\u003e\n        \n\n        \n\n        \n\n        \n\n        \u003cdiv class=\"section-row\"\u003e\n            \u003cdiv class=\"row-key\"\u003eCertificate of Analysis (COA)​\u003c\/div\u003e\n            \u003cdiv class=\"row-value\"\u003e\n                \u003cdiv class=\"coa-search-container\"\u003e\n                    \u003cinput id=\"coa-link-input\" type=\"text\" placeholder=\"Enter Lot No.\"\u003e\n                    \u003cbutton id=\"coa-search-button\"\u003e\n                        \u003cdiv class=\"coa-search-button-content\"\u003e\n                            \u003csvg class=\"search-spin\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\" viewbox=\"0 0 200 200\"\u003e\u003cradialgradient id=\"a7\" cx=\".66\" fx=\".66\" cy=\".3125\" fy=\".3125\" gradienttransform=\"scale(1.5)\"\u003e\u003cstop offset=\"0\" stop-color=\"#FFFFFF\"\u003e\u003c\/stop\u003e\u003cstop offset=\".3\" stop-color=\"#FFFFFF\" stop-opacity=\".9\"\u003e\u003c\/stop\u003e\u003cstop offset=\".6\" stop-color=\"#FFFFFF\" stop-opacity=\".6\"\u003e\u003c\/stop\u003e\u003cstop offset=\".8\" stop-color=\"#FFFFFF\" stop-opacity=\".3\"\u003e\u003c\/stop\u003e\u003cstop offset=\"1\" stop-color=\"#FFFFFF\" stop-opacity=\"0\"\u003e\u003c\/stop\u003e\u003c\/radialgradient\u003e\u003ccircle transform-origin=\"center\" fill=\"none\" stroke=\"url(#a7)\" stroke-width=\"15\" stroke-linecap=\"round\" stroke-dasharray=\"200 1000\" stroke-dashoffset=\"0\" cx=\"100\" cy=\"100\" r=\"70\"\u003e\u003canimatetransform type=\"rotate\" attributename=\"transform\" calcmode=\"spline\" dur=\"2\" values=\"360;0\" keytimes=\"0;1\" keysplines=\"0 0 1 1\" repeatcount=\"indefinite\"\u003e\u003c\/animatetransform\u003e\u003c\/circle\u003e\u003ccircle transform-origin=\"center\" fill=\"none\" opacity=\".2\" stroke=\"#FFFFFF\" stroke-width=\"15\" stroke-linecap=\"round\" cx=\"100\" cy=\"100\" r=\"70\"\u003e\u003c\/circle\u003e\u003c\/svg\u003e\n                            \u003cspan\u003eSearch\u003c\/span\u003e\n                        \u003c\/div\u003e\n                    \u003c\/button\u003e\n                    \u003cspan class=\"coa-not-found\"\u003eCOA not found\u003c\/span\u003e\n                \u003c\/div\u003e\n            \u003c\/div\u003e\n        \u003c\/div\u003e\n\n    \u003c\/div\u003e\n\n    \u003c!-- General Info --\u003e\n    \n\n    \u003c!-- Properties --\u003e\n    \n\n    \u003c!-- Safety Info --\u003e\n    \n\n    \u003c!-- Application  --\u003e\n    \n    \u003ch2 class=\"section-header\"\u003eApplication\u003c\/h2\u003e\n    \u003cdiv class=\"html-area\"\u003e\n        Technical Notes:\u003cbr\u003e1. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products 1.2. These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, ß-ketoesters and simple alkenes.4-B\u003cbr\u003e2.Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.\u003cbr\u003e3.Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides .\u003cbr\u003e4. Asymmetric hydrogenation of ketones and phos phinylketimines .\u003cbr\u003e5.Michael addition of Grignard reagents to a,a-unsaturated esters and thioesters.\u003cbr\u003e6.Boration of a,a-unsaturated esters and nitriles.\u003cbr\u003e7.Reaction of aryl halides with ammonia.\u003cbr\u003e8.Cu-catalyzed reduction of activated c=c bonds with PMHS.\u003cbr\u003e9. Regio- and enantioselective hydroboration of vinyl arenes.\u003cbr\u003e10. Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes .\u003cbr\u003e11.1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.\u003cbr\u003e12.Catalyst for the homodimerization of ketoketenes.\u003cbr\u003e13.L igand for the Rh catalyzed synthesis of lactones.\u003cbr\u003e14.L igand for the Cu-catalyzed synthesis of syn and antiẞ-amino alcohols.\u003cbr\u003e15. L igand for Rh-catalyzed Asymmetric Hydrosilylation of Dehydroalanine\n    \u003c\/div\u003e\n    \n\n    \u003c!-- Faq --\u003e\n    \n\n    \u003c!-- References --\u003e\n    \n\n\n    \u003cscript\u003e\n        const coaSearchButton = document.getElementById('coa-search-button');\n        coaSearchButton.addEventListener('click', async function() {\n            const coaLinkInput = document.getElementById('coa-link-input');\n            const spinElement = document.querySelector('.search-spin');\n            const notFoundElement = document.querySelector('.coa-not-found');\n\n            const lot = coaLinkInput.value.trim().toUpperCase();\n            if (lot.length \u003e 0) {\n                spinElement.style.display = 'block';\n                notFoundElement.style.display = 'none';\n\n                const url = `https:\/\/web.jkchemical.com\/partial\/coaFileLotNumber\/${lot}`;\n                await fetch(url).then((res) =\u003e {\n                    if (res.status === 200) {\n                        window.open(url, '_blank');\n                    } else {\n                        notFoundElement.style.display = 'block';\n                    }\n                }).finally(() =\u003e {\n                    spinElement.style.display = 'none';\n                });\n            }\n        });\n    \u003c\/script\u003e\n\n\n\u003c\/div\u003e","brand":"US-Strem","offers":[{"title":"1×100mg","offer_id":45332437827774,"sku":"SC26-1175_100_MG","price":111.0,"currency_code":"USD","in_stock":true},{"title":"1×2g","offer_id":45332437860542,"sku":"SC26-1175_2_G","price":1062.0,"currency_code":"USD","in_stock":true},{"title":"1×10g","offer_id":45332437893310,"sku":"SC26-1175_10_G","price":4511.0,"currency_code":"USD","in_stock":true},{"title":"1×500mg","offer_id":45332437926078,"sku":"SC26-1175_500_MG","price":387.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0506\/0005\/0878\/files\/60be0f2910a21f23c36ac79c2cb1c809.jpg?v=1776385346","url":"https:\/\/www.jk-sci.com\/products\/q8826-1175","provider":"J\u0026K Scientific LLC","version":"1.0","type":"link"}